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Influence of post-deposition heat treatment on electrical transport properties of In2S3-buffered Cu(In,Ga)Se2 cells

Identifieur interne : 000A42 ( Main/Repository ); précédent : 000A41; suivant : 000A43

Influence of post-deposition heat treatment on electrical transport properties of In2S3-buffered Cu(In,Ga)Se2 cells

Auteurs : RBID : Pascal:13-0229202

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English descriptors

Abstract

The electrical characteristics of Cu(In,Ga)Se2-based solar cells with In2S3 buffer were investigated. The effects of post-deposition annealing in helium or in air on current-voltage characteristics, net acceptor density profiles and admittance spectra were studied. Analysis of the current-voltage characteristics showed that interface recombination dominated transport in the as-deposited devices was reduced after annealing and partially replaced by bulk recombination. This was accompanied by a decrease in the saturation current and diode ideality factor. The influence of the heat treatment on the buffer/hetero-interface region as determined by capacitance measurements was minor. We conclude that a reduction in the interface states density and in the p + layer doping caused by the chemical modification of the hetero-interface region is the major source of the improvement.

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Pascal:13-0229202

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<title xml:lang="en" level="a">Influence of post-deposition heat treatment on electrical transport properties of In
<sub>2</sub>
S
<sub>3</sub>
-buffered Cu(In,Ga)Se
<sub>2 </sub>
cells</title>
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<name sortKey="Abdel Maksoud, H" uniqKey="Abdel Maksoud H">H. Abdel Maksoud</name>
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<name sortKey="Igalson, M" uniqKey="Igalson M">M. Igalson</name>
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<term>Diodes</term>
<term>Electrical characteristic</term>
<term>Electrical properties</term>
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<term>Gallium selenides</term>
<term>Heat treatments</term>
<term>IV characteristic</term>
<term>Indium selenides</term>
<term>Indium sulfide</term>
<term>Interface states</term>
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<div type="abstract" xml:lang="en">The electrical characteristics of Cu(In,Ga)Se
<sub>2</sub>
-based solar cells with In
<sub>2</sub>
S
<sub>3</sub>
buffer were investigated. The effects of post-deposition annealing in helium or in air on current-voltage characteristics, net acceptor density profiles and admittance spectra were studied. Analysis of the current-voltage characteristics showed that interface recombination dominated transport in the as-deposited devices was reduced after annealing and partially replaced by bulk recombination. This was accompanied by a decrease in the saturation current and diode ideality factor. The influence of the heat treatment on the buffer/hetero-interface region as determined by capacitance measurements was minor. We conclude that a reduction in the interface states density and in the p + layer doping caused by the chemical modification of the hetero-interface region is the major source of the improvement.</div>
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<sub>2</sub>
-based solar cells with In
<sub>2</sub>
S
<sub>3</sub>
buffer were investigated. The effects of post-deposition annealing in helium or in air on current-voltage characteristics, net acceptor density profiles and admittance spectra were studied. Analysis of the current-voltage characteristics showed that interface recombination dominated transport in the as-deposited devices was reduced after annealing and partially replaced by bulk recombination. This was accompanied by a decrease in the saturation current and diode ideality factor. The influence of the heat treatment on the buffer/hetero-interface region as determined by capacitance measurements was minor. We conclude that a reduction in the interface states density and in the p + layer doping caused by the chemical modification of the hetero-interface region is the major source of the improvement.</s0>
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<s5>14</s5>
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<s0>Sulfure d'indium</s0>
<s5>15</s5>
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<s1>E-MRS Spring Meeting 2012. Symposium B "Thin Film Chalcogenide Photovoltaic Materials"</s1>
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<s4>2012-05-14</s4>
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